(12) Translation of european patent specification

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1 (12) Translation of european patent specification (11) NO/EP B1 (19) NO NORWAY (51) Int Cl. C09K 8/36 ( ) B01F 17/00 ( ) Norwegian Industrial Property Office (21) Translation Published (80) Date of The European Patent Office Publication of the Granted Patent (86) European Application Nr (86) European Filing Date (87) The European Application s Publication Date (30) Priority , US, (84) Designated Contracting States: AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO SE SI SK SM TR (73) Proprietor Clearwater International LLC, 2000 St. James Place, Houston, TX 77056, US-USA (72) Inventor Falana, Olusegun Matthew, 310 Fontana Albero, San AntonioTexas 78253, US- USA Gilmer, Arthur T., 147 W. Slatestone Circle, SpringTexas 77382, US-USA Marshall, Edward, 3500 Sherman Drive, SehuteTexas 78154, US-USA (74) Agent or Attorney Tandbergs Patentkontor AS, Postboks 1570 Vika, 0118 OSLO, Norge (54) Title Secondary emulsifiers for inverted emulsion fluids and methods for making an using same (56) References Cited: US-A US-A US-B Anonymous: "CAS DataBase List: CAS "[Online] 1 January 2008 ( ), XP Chemical Book Retrieved from the Internet: URL:http://www.chemicalbook.com/CASEN_ htm> [retrieved on ]

2 Enclosed is a translation of the patent claims in Norwegian. Please note that as per the Norwegian Patents Acts, section 66i the patent will receive protection in Norway only as far as there is agreement between the translation and the language of the application/patent granted at the EPO. In matters concerning the validity of the patent, language of the application/patent granted at the EPO will be used as the basis for the decision. The patent documents published by the EPO are available through Espacenet (http://worldwide.espacenet.com) or via the search engine on our website here: https://search.patentstyret.no/

3 1 EP Patentkrav 1. Oljebasert borefluidsammensetning omfattende: en kontinuerlig fase omfattende en organisk flytende base, en diskontinuerlig fase omfattende en vandig væske, et emulgerende system, et vektmateriale, og et viskositetsgivende middel, hvor emulgeringssystemet omfatter et primært emulgeringsmiddel eller et flertall av primære emulgatorer, og en sekundær emulgator eller et flertall av sekundære emulgatorer, karakterisert ved at de sekundære emulgatorer er forbindelser med de generelle formler (II-VI): (b) Z 1 er et halogenatom, R-gruppe, SO 3 R 3 -gruppe, OPO 2 R 3 -gruppe, eller og 12 karbonatomer, (c) Z 2 er et hydrogenatom, NHR 2 -gruppe, OR 2 - gruppe, SiH 2 R 2 -gruppe, PHR 2 -gruppe, eller SR 2 -gruppe, hvor R 2 er en karbylgruppe med mellom 1 og 40 karbonatomer, (d) R 5 er et hydrogenatom eller en karbylgruppe, (e) R 6 er et hydrogenatom eller en karbylgruppe, og (f) R 7 er et hydrogenatom eller en karbylgruppe, hvor karbylgruppen har mellom 1 karbonatom og 10 karbonatomer, og hvor en eller flere av karbonatomene i R, R 1, R 2, R 5, R 6, eller R 7 kan være erstattet med N, O, S og/eller blandinger,

4 2 (b) Z 1 er et halogenatom, R-gruppe, SO 3 R 3 -gruppe, OPO 2 R 3 -gruppe, eller og 12 karbonatomer, og (c)z 2 er et hydrogenatom, NHR 2 -gruppe, OR 2 - gruppe, SiH 2 R 2 -gruppe, PHR 2 -gruppe, eller SR 2 -gruppe, hvor R 2 er en karbylgruppe med mellom 1 og 40 karbonatomer, og hvor ett eller flere av karbonatomene i R, R 1, R 2 eller R 3 kan være erstattet med N, O, S og/eller blandinger derav, (b) Z 1 er et halogenatom, R-gruppe, SO 3 R 3 -gruppe, OPO 2 R 3 -gruppe eller og 12 karbonatomer, (c) R 2 er en karbylgruppe med mellom 1 og 40 karbonatomer, og hvor ett eller flere av karbonatomene i R, R 1, R 2 eller R 3 kan være erstattet med N, O, S og/eller blandinger derav,

5 3 (b) R 2 er en karbylgruppe med mellom 1 og 40 karbonatomer, og hvor ett eller flere av karbonatomene i R 3 eller R 2 kan være erstattet med N, O, S og/eller blandinger derav; eller hvor R 1 er en karbylgruppe med mellom 10 og 40 karbonatomer, og hvor en eller flere av karbonatomene i R 1 kan være erstattet med N, O, S og/eller blandinger derav. 2. Sammensetning ifølge krav 1, karakterisert ved at den organiske væskebasen er valgt fra gruppen bestående av dieselolje, mineralolje, ester, poly-alfa-olefin, mono-eter, dieter, lineær alkylbenzen og blandinger derav. 3. Fremgangsmåte for boring av en underjordisk brønn med et oljebasert borefluid, omfattende: formulering av oljebasert borefluid omfattende: en kontinuerlig fase omfattende en organisk flytende base,

6 4 en diskontinuerlig fase omfattende en vandig væske, et emulgerende system, et vektmateriale, og en viskositetsgivende middel, hvor emulgeringssystemet omfatter et primært emulgeringsmiddel eller et flertall av primære emulgatorer, og en sekundær emulgator eller et flertall av sekundære emulgatorer, karakterisert ved at de sekundære emulgatorer er forbindelser med de generelle formler (II-VI): (b) Z 1 er et halogenatom, R-gruppe, SO 3 R 3 -gruppe, OPO 2 R 3 -gruppe, eller, og hvor R 3 er et hydrogenatom eller en karbylgruppe med mellom 1 og 12 karbonatomer, (c) Z 2 er et hydrogenatom, NHR 2 -gruppe, OR 2 - gruppe, SiH 2 R 2 -gruppe, PHR 2 -gruppe, eller SR 2 -gruppe, hvor R 2 er en karbylgruppe med mellom 1 og 40 karbonatomer, (d) R 5 er et hydrogenatom eller en karbylgruppe, (e) R 6 er et hydrogenatom eller en karbylgruppe, og (f) R 7 er et hydrogenatom eller en karbylgruppe, hvor karbylgruppen har mellom 1 karbonatom og 10 karbonatomer, og hvor en eller flere av karbonatomene i R, R 1, R 2, R 5, R 6 eller R 7 kan være erstattet med N, O, S og/eller blandinger derav;

7 5 (b) Z 1 er et halogenatom, R-gruppe, SO 3 R 3 -gruppe, OPO 2 R 3 -gruppe, eller og 12 karbonatomer, og (c) Z 2 er et hydrogenatom, NHR 2 -gruppe, OR 2 - gruppe, SiH 2 R 2 -gruppe, PHR 2 -gruppe, eller SR 2 -gruppe, hvor R 2 er en karbylgruppe med mellom 1 og 40 karbonatomer, og hvor ett eller flere av karbonatomene i R, R 1, R 2 eller R 3 kan være erstattet med N, O, S og/eller blandinger derav; (b) Z 1 er et halogenatom, R-gruppe, SO 3 R 3 -gruppe, OPO 2 R 3 -gruppe eller og 12 karbonatomer, (c) R 2 er en karbylgruppe med mellom 1 og 40 karbonatomer, og hvor ett eller flere av karbonatomene i R, R 1, R 2 eller R 3 kan være erstattet med N, O, S og/eller blandinger derav; (b) R 2 er en karbylgruppe med mellom 1 og 40 karbonatomer, og hvor ett

8 6 eller flere av karbonatomene i R 1 eller R 2 kan være erstattet med N, O, S og/eller blandinger derav; eller hvor R 1 er en karbylgruppe med mellom 10 og 40 karbonatomer, og hvor en eller flere av karbonatomene i R 1 kan være erstattet med N, O, S og/eller blandinger derav. 4. Fremgangsmåte ifølge krav 3, karakterisert ved at den organiske væskebasen er valgt fra gruppen bestående av dieselolje, mineralolje, ester, poly-alfa-olefin, mono-eter, dieter, lineær alkylbenzen og blandinger derav. 5. Sekundær emulgeringssammensetning omfattende: en eller et flertall av sekundære emulgatorer, karakterisert ved at de sekundære emulgatorene er forbindelser med de generelle formler (II- VI): (b) Z 1 er en R-gruppe, SO 3 R 3 -gruppe, OPO 2 R 3 -gruppe, eller OPO 3 R 3 - gruppe, hvor R er en karbylgruppe med mellom 1 og 40 karbonatomer og

9 7 der R 3 er et hydrogenatom eller en karbylgruppe med mellom 1 og 12 karbonatomer, (c) Z 2 er et hydrogenatom, NHR 2 -gruppe, OR 2 -gruppe, SiH 2 R 2 -gruppe, PHR 2 -gruppe, eller SR 2 -gruppe, hvor R 2 er en karbylgruppe med mellom 1 og 40 karbonatomer, (d) R 5 er et hydrogenatom eller en karbylgruppe, (e) R 6 er et hydrogenatom eller en karbylgruppe, og (f) R 7 er et hydrogenatom eller en karbylgruppe, hvor karbylgruppen har mellom 1 karbonatom og 10 karbonatomer, og hvor en eller flere av karbonatomene i R, R 1, R 2, R 5, R 6 eller R 7 kan være erstattet med N, O, S og/eller blandinger; (b) Z 1 er et halogenatom, R-gruppe, SO 3 R 3 -gruppe, OPO 2 R 3 -gruppe, eller og 12 karbonatomer, og (c) Z 2 er et hydrogenatom, NHR 2 -gruppe, OR 2 - gruppe, SiH 2 R 2 -gruppe, PHR 2 -gruppe, eller SR 2 -gruppe, hvor R 2 er en karbylgruppe med mellom 1 og 40 karbonatomer, og hvor ett eller flere av karbonatomene i R, R 1, R 2 eller R 3 kan være erstattet med N, O, S og/eller blandinger derav;

10 8 (b) Z 1 er et halogenatom, R-gruppe, SO 3 R 3 -gruppe, OPO 2 R 3 -gruppe eller og 12 karbonatomer, (c) R 2 er en karbylgruppe med mellom 1 og 40 karbonatomer, og hvor ett eller flere av karbonatomene i R, R 1, R 2 eller R 3 kan være erstattet med N, O, S og/eller blandinger derav; (b) R 2 er en karbylgruppe med mellom 1 og 40 karbonatomer, og hvor ett eller flere av karbonatomene i R 1 eller R 2 kan være erstattet med N, O, S og/eller blandinger derav; eller hvor R 1 er en karbylgruppe med mellom 10 og 40 karbonatomer, og hvor en eller flere av karbonatomene i R 1 kan være erstattet med N, O, S og/eller blandinger derav.

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