(12) Translation of european patent specification

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1 (12) Translation of european patent specification (11) NO/EP B1 (19) NO NORWAY (1) Int Cl. G01J 1/0 ( ) Norwegian Industrial Property Office (21) Translation Published (80) Date of The European Patent Office Publication of the Granted Patent (86) European Application Nr (86) European Filing Date (87) The European Application s Publication Date (30) Priority , GB, (84) Designated Contracting States: AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO SE SI SK SM TR (73) Proprietor Intellego Technologies AB, Medicinaregatan 8A, Gothenburg, SE-Sverige (72) Inventor MILLS, Andrew, Dept of Pure and Applied ChemistryUniversity of Strathclyde0 George Street, Glasgow G1 1QE, GB-Storbritannia MCFARLANE, Michael, Dept of Pure and Applied ChemistryUniversity of Strathclyde0 George Street, Glasgow G1 1QE, GB-Storbritannia MCDIARMID, Kate, Dept of Pure and Applied ChemistryUniversity of Strathclyde0 George Street, Glasgow G1 1QE, GB-Storbritannia GROSSHANS, Pauline, Dept of Pure and Applied ChemistryUniversity of Strathclyde0 George Street, Glasgow G1 1QE, GB-Storbritannia (4) Title DOSE RESPONSIVE UV INDICATOR (6) References Cited: WO-A1-94/03 US-A US-A US-A US-A ABDEL-FATTAH A A ET AL: "Thymol-blue dyed poly(vinyl butyral) films for monitoring ultraviolet radiation" JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY, A: CHEMISTRY, ELSEVIER SEQUOIA, LAUSANNE, CH, vol. 137, no. 1, 24 October 2000 ( ), pages 37-43, XP ISSN: [retrieved on ]

2 Enclosed is a translation of the patent claims in Norwegian. Please note that as per the Norwegian Patents Acts, section 66i the patent will receive protection in Norway only as far as there is agreement between the translation and the language of the application/patent granted at the EPO. In matters concerning the validity of the patent, language of the application/patent granted at the EPO will be used as the basis for the decision. The patent documents published by the EPO are available through Espacenet (http://worldwide.espacenet.com) or via the search engine on our website here: https://search.patentstyret.no/

3 1 PATENTKRAV 1 1. UV-strålings(UVR)-responderende indikator som innbefatter et første stoff følsomt for UVB- og/eller UVA-stråling som er modifisert slik at det viser en endret egenskap på en forsinket måte som respons på eksponering for UVB- og/eller UVA-stråling, idet det første UVB- og/eller UVA-strålingsfølsomme stoffet innbefatter et UVB- og/eller UVA-strålingsdrevet syrefrigjøringsmiddel og en ph-indikator som viser endret farge mellom deprotonert og sur form, idet det UVB- og/eller UVAstrålingsdrevne syrefrigjøringsmidlet omfatter et fargestoff som innbefatter et jodonium- eller sulfoniumsalt, og idet det første UVB- og/eller UVA-strålingsfølsomme stoffet også innbefatter et protonopptaksmiddel for å forsinke protoneringen av ph-indikatoren gjennom det UVB- og/eller UVA-strålingsdrevne syrefrigjøringsmidlet, idet protonopptaksmidlet er en base Den UVR-responderende indikatoren ifølge krav 1, der det første UVBog/eller UVA-strålingsfølsomme stoffet er modifisert slik at det får andre egenskaper som respons på forskjellige MED-verdier, som 0,, 1,0, 1,, 2,0 og 2, Den UVR-responderende indikatoren ifølge krav 1 til bruk for å indikere eksponering for UVB- og/eller UVA-stråling gjennom en tidsperiode, idet UVindikatoren også innbefatter et andre UVB- og/eller UVA-strålingsfølsomt stoff som kan vise en endret egenskap momentant ved eksponering for UVB- og/eller UVAstråling UVR-indikatoren ifølge krav 3 der både det momentane og det forsinkede UVB- og/eller UVA-strålingsfølsomme stoffet får responsegenskapene sine endret ved hjelp av et UV-filtreringsmiddel.. UVR-indikatoren ifølge noen av krav 3 4, der det første og det andre UVB- og/eller UVA-følsomme stoffet viser en endret egenskap som stort sett er irreversibel etter eksponering for UVB- og/eller UVA-stråling.

4 2 6. UVR-indikatoren ifølge noen av de foregående kravene der det UVBog/eller UVA-strålingsdrevne syrefrigjøringsmidlet er valgt fra lista som består av difenyljodoniumklorid (DPIC), DPI-heksalfluorofosfat, DPI-perfluor-1-butansulfonat, DPI-triflat, 4-jodfenyldifenylsulfoniumtriflat (IDST), 4-metyltiofenyl-DST, 2-naftyl- DST, 4-klorfenyl-DST og 4-bromfenyl-DST, og ph-indikatoren er valgt fra lista som består av tymolblått (TB ), malakittgrønt (MG), bromkresolgrønt (BG), indofenolblått (IB), 1,4-bis(isopropylamino)antrakinon (WB), hydroksyetylaminoazobenzen, metylrødt (MR), fenolrødt (PhR) og ethvert annet di-/trifenylmetanfargestoff, aminoazofargestoff, aminoantrakinonfargestoff eller andre ph-følsomme fargestoff. 7. UVR-indikatoren ifølge noen av de foregående kravene der protonopptaksmidlet er NaOH, Na 2 CO 3, NaHCO 3, NH 4 OH eller Ca(OH) UVR-responderende indikator ifølge noen av kravene 3 7, der det første («forsinkede») og det andre («momentane») UVR-følsomme stoffet foreligger i form av trykkfarge som kan påføres et underlag eller liknende UVR-indikatoren ifølge noen av kravene 3 8 der den endrede egenskapen til det første og det andre UVB- og/eller UVA-strålingsfølsomme stoffet sammen gir en visuell indikasjon på UVB- og/eller UVA-dosen, vanligvis over tid, og eventuelt der den endrede egenskapen til det første og det andre UVBog/eller UVA-strålingsfølsomme stoffet kan skilles fra hverandre, og eventuelt der den endrede egenskapen er en fargeendring. 30. UVR-indikatoren ifølge krav 9 der det andre momentane UVB- og/eller UVA-strålingsfølsomme stoffet kan endre en egenskap, for eksempel endre farge som respons på en første opprinnelig dose/et første opprinnelig nivå av UVBog/eller UVA-stråling, og det første forsinkede UVB- og/eller UVAstrålingsfølsomme stoffet kan endre en egenskap, som for eksempel farge, som respons på økt dose av UVB- og/eller UVA-stråling,

5 3 og eventuelt der fargeendringer kan visualiseres separat ved hjelp av egne områder av det første og det andre UVB- og/eller UVA-strålingsfølsomme stoffet, og eventuelt der det første og det andre UVB- og UVA-strålingsfølsomme stoffet er trykt oppå hverandre med progressivt varierende fargeendringer, og eventuelt der underlaget er farget slik at det matcher/svarer til en opprinnelig eller endret farge på trykkfargen slik at trykkfargen kan trykkes på en bestemt måte slik at det viser eller skjuler et bilde som respons på UVB- og/eller UVA-stråling. 11. UVR-indikatoren ifølge noen av de foregående kravene, som innbefatter en sammensetning som er følsom for både UVA og UVB ( nm) og en annen som bare er følsom for UVB Framgangsmåte for å detektere en dose av UVR mottatt av en UVindikator, som innbefatter trinnene å: tilveiebringe en UV-indikator som innbefatter et stoff følsomt for UVBog/eller UVA-stråling, modifisert slik at det viser en endret egenskap på en forsinket måte etter eksponering for UVB- og/eller UVA-stråling, og detektere UV-indikatorens grad av eksponering for UVB- og/eller UVAstråling på grunnlag av den viste endrede egenskapen ved det UVB- og/eller UVAstrålingsfølsomme stoffet, idet det første UVB- og/eller UVA-strålingsfølsomme stoffet innbefatter et syrefrigjøringsmiddel som drives av UVB- og/eller UVA-stråling og en ph-indikator som endrer farge mellom deprotonert og sur form, idet det UVB- og/eller UVAstrålingsdrevne syrefrigjørende midlet omfatter et fargestoff som innbefatter et jodonium- eller sulfoniumsalt, og idet det første UVB- og/eller UVA-strålingsfølsomme stoffet også innbefatter et protonopptaksmiddel for å forsinke protoneringen av ph-indikatoren gjennom det UVB- og/eller UVA-strålingsdrevne syrefrigjøringsmidlet, idet protonopptaksmidlet er en base. 13. Framgangsmåten ifølge krav 12 som også innbefatter å sammenlikne alle viste endrede egenskaper etter eksponering for UVB- og/eller UVA-stråling med

6 4 referanseegenskaper som svarer til kjente UV-doser for å bidra til å detektere/bestemme den relative UV-dosen som er mottatt av indikatoren. 14. Framgangsmåten ifølge noen av kravene 12 og 13, der eksponering for UVB- og/eller UVA-stråling skyldes eksponering for sollys eller solariumstråling. 1. Framgangsmåten ifølge noen av kravene 12 til 14, der det UVB- og/eller UVA-følsomme stoffet er modifisert slik at det viser den endrede egenskapen sin som respons på forskjellige MED-verdier, som 0,, 1,0, 1,, 2,0 og 2,.

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(12) Translation of european patent specification

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(12) Translation of european patent specification

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(12) Translation of european patent specification

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(12) Translation of european patent specification

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(12) Translation of european patent specification

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(12) Translation of european patent specification

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(12) Translation of european patent specification

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(12) Translation of european patent specification

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(12) Translation of european patent specification

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(12) Translation of european patent specification

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(12) Translation of european patent specification

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(12) Translation of european patent specification

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(12) Translation of european patent specification

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(12) Translation of european patent specification

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(12) Translation of european patent specification

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(12) Translation of european patent specification

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(12) Translation of european patent specification

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(12) Translation of european patent specification

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(12) Translation of european patent specification

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(12) Translation of european patent specification

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(12) Translation of european patent specification

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(12) Translation of european patent specification

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(12) Translation of european patent specification

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(12) Translation of european patent specification

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(12) Translation of european patent specification

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(12) Translation of european patent specification

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(12) Translation of european patent specification

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(12) Translation of european patent specification

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(12) Translation of european patent specification

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(12) Translation of european patent specification

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(12) Translation of european patent specification

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(12) Translation of european patent specification

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(12) Translation of european patent specification

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(12) Translation of european patent specification

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(12) Translation of european patent specification

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(12) Translation of european patent specification

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(12) Translation of european patent specification

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(12) Translation of european patent specification

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(12) Translation of european patent specification

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(12) Translation of european patent specification

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(12) Translation of european patent specification

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(12) Translation of european patent specification

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(12) Translation of european patent specification

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(12) Translation of european patent specification

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(12) Translation of european patent specification

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(12) Translation of european patent specification

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