(12) Translation of european patent specification

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1 (12) Translation of european patent specification (11) NO/EP B1 (19) NO NORWAY (1) Int Cl. D21H 19/36 (06.01) D21H 17/46 (06.01) D21H 17/2 (06.01) D21H 17/6 (06.01) D21H 19/40 (06.01) D21H 19/62 (06.01) D21H 19/80 (06.01) D21H 19/82 (06.01) D21H 21/ (06.01) D21H 27/ (06.01) Norwegian Industrial Property Office (21) Translation Published (80) Date of The European Patent Office Publication of the Granted Patent (86) European Application Nr (86) European Filing Date (87) The European Application s Publication Date () Priority , US, , US, (84) Designated Contracting States: Designated Extension States: AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO SE SI SK SM TR BA ME RS (73) Proprietor Solenis Technologies Cayman, L.P., Rheinweg 11, 80 Schaffhausen, CH-Sveits (72) Inventor BRUNGARDT, Clement, L., 70 Waterway Road,, Oxford,PA 19363, US-USA (74) Agent or Attorney Zacco Norway AS, Postboks 03 Vika, 012 OSLO, Norge (4) Title CATIONIC WET STRENGTH RESIN MODIFIED PIGMENTS IN WATER-BASED LATEX COATING APPLICATIONS (6) References Cited: WO-A2-01/649 WO-A2-04/ US-A US-A US-A

2 Enclosed is a translation of the patent claims in Norwegian. Please note that as per the Norwegian Patents Acts, section 66i the patent will receive protection in Norway only as far as there is agreement between the translation and the language of the application/patent granted at the EPO. In matters concerning the validity of the patent, language of the application/patent granted at the EPO will be used as the basis for the decision. The patent documents published by the EPO are available through Espacenet ( or via the search engine on our website here: NO/EP

3 1 Patentkrav 1. Fremgangsmåte for å belegge et papir- eller pappark, omfattende: (a) å belegge minst én side av papir- eller papparket med en dispersjon som har et kationisk zeta-potensial omfattende (1) en blanding inneholdende én eller flere anioniske pigmenter valgt fra gruppen bestående av talkum, kaolinleire, bentonittleire og laponitt i en mengde på minst ca. % tørrvekt av blandingen og (2) én eller flere kationiske polyamin-epihalohydrin-våtstyrkeharpikser ved en beleggingsvekt fra ca. 0,1 g/m 2 til ca. g/m 2 ; og (b) tørke det belagte papir- eller papparket, anionisk pigment er fra ca. 0,01:1 til ca. 2:1 og hvori epihalohydrinet er epiklorhydrin Fremgangsmåten ifølge krav 1, ytterligere omfattende: å belegge det tørkede papir- eller papparket med et toppbelegg av funksjonell barriere formulert for å tilveiebringe motstand mot én eller flere av de følgende: (1) flytende vann, (2) vanndamp, (3) olje, (4) fett, () gasspermeabilitet, (6) utglidning eller (7) statisk elektrisitet. 3. Fremgangsmåten ifølge krav 1 ytterligere omfattende å belegge det tørkede papir- eller papparket med et vannbasert pigmentbelegg Fremgangsmåten ifølge krav 1 hvori et vannløselig bindemiddel omfatter opp til ca. 80 % tørrvekt av den anioniske pigmentoldige blandingen, og bindemiddelet er valgt fra gruppen bestående av: nøytrale naturlige vannløselige polymerbindemidler; kationiske naturlige vannløselige polymerbindemidler; nøytrale syntetiske vannløselige polymerbindemidler; og kationiske syntetiske polymerbindemidler.. Fremgangsmåten ifølge krav 1 hvori den anioniske pigmentholdige blandingen er fra ca. 2 % til ca. 0 % tørrvekt av blandingen av enten bentonittleire eller laponitt, eller minst ca. 2 % tørrvekt av blandingen av enten kaolinleire eller talkum, eller fra ca. 0 % til ca. 0 % tørrvekt av blandingen av enten kaolinleire eller talkum.

4 2 6. Fremgangsmåten ifølge krav 1 hvori vektforholdet mellom kationisk polyaminepihalohydrin-våtstyrkeharpiks og anionisk pigment er fra ca. 0,01:1 til 1,:1, eller fra ca. 0,6:1 til ca. 0,8:1 eller fra ca. 0,01:1 til ca. 0,2: Fremgangsmåten ifølge krav 4 hvori det vannløselige polymerbindemiddelet er én eller flere fra gruppen bestående av: stivelse; etylert stivelse; kationisk stivelse; oksidert stivelse; enzymomdannet stivelse; alginater; kasein; cellulosederivater, foretrukket én eller flere fra gruppen bestående av hydroksyetylcellulose, metylhydroksyetylcellulose, metylcellulose, hydroksypropylcellulose og hydroksypropylguar; polyvinylalkohol; etylen- /vinylalkoholkopolymerer; polyvinylamin; polyakrylamid; polyakrylamidkopolymerer; glyoksylert polyakrylamid; polydiallylamin; polydiallylaminkopolymerer; polydimetyldiallylamin og polydimetyldiallylaminkopolymerer. 8. Fremgangsmåten ifølge krav 2 der toppbelegg av funksjonell barriere inneholder en vannbasert polymerlateks og eventuelt inneholder én eller flere av følgende: (1) en naturlig eller syntetisk vannløselig polymer, (2) et pigment, (3) en voks, (4) en kryssbinder og () et limemiddel. 9. Fremgangsmåten ifølge krav 2, hvori toppbelegget av funksjonell barriere påføres med en beleggvekt på ikke mer enn ca. 2 g/m Fremgangsmåten ifølge 3 hvori det vannbaserte pigmentbelegget omfatter et anionisk polymert lateksbindemiddel og minst ett og pigment Dispersjon som har et kationisk zeta-potensial for bruk som et basisbelegg på et papir- eller pappark som primer for et toppbelegg av funksjonell barriere eller pigmentbelegg omfattende: (a) en anionisk pigmentholding blanding omfattende én eller flere anioniske pigmenter valgt fra gruppen bestående av talkum, kaolinleire, bentonittleire og laponitt i en mengde på minst ca. % tørrvekt av blandingen, og (b) én eller flere kationiske polyamin-epihalohydrin-våtstyrkeharpikser, anionisk pigment er fra ca. 0,01:1 til ca. 2:1 og hvori epihalohydrinet er epiklorhydrin.

5 3 12. Dispersjonen ifølge krav 11 hvori det anioniske pigmentet er talkum eller kaolinleire, og vektforholdet mellom kationisk våtstyrkeharpiks og anionisk pigment er fra ca. 0,03:1 til ca. 0,2:1, eller det anioniske pigmentet er bentonittleire, og vektforholdet mellom kationisk våtstyrkeharpiks og anionisk pigment er fra ca. 0,6:1 til ca. 0,8: Dispersjonen ifølge krav 11 eller fremgangsmåten ifølge krav 1 hvori den kationiske polyamin-epihalohydrin-våtstyrkeharpiksen er valgt fra gruppen bestående av: polyaminopolyamid-epiklorhydrin-harpikser, slik som polyaminoamid-epiklorhydrin-harpikser, polyamidpolyamin-epiklorhydrinharpikser, polyaminpolyamid-epiklorhydrin-harpikser, aminopolyamidepiklorhydrin-harpikser, og polyamid-epiklorhydrin-harpikser; polyalkylenpolyamin-epiklorhydrin-harpikser; polyaminourylen-epiklorhydrin-harpikser; kopolyamid-polyurylen-epiklorhydrin-harpikser; og polyamid-polyurylenepiklorhydrin-harpikser Laminat omfattende et første papirlag belagt med et andre lag av (a) en dispersjon som har et kationisk zeta-potensial omfattende én eller flere anioniske pigmenter valgt fra gruppen bestående av talkum, kaolinleire, bentonittleire og laponitt i en mengde på minst ca. % tørrvekt av blandingen, og (b) én eller flere kationiske polyamin-epihalohydrin-våtstyrkeharpikser hvori det andre laget eventuelt er belagt med et tredje lag omfattende et lateksbelegg av funksjonell barriere formulert for å tilveiebringe motstand mot én eller flere av følgende: (1) flytende vann, (2) vanndamp, (3) olje, (4) fett, () gasspermeasjon, (6) utglidning, (7) statisk elektrisitet eller laminatet eventuelt ytterligere omfatter et tredje lag på det andre laget, der det tredje laget omfatter et anionisk latekspigmentbelegg, anionisk pigment er fra ca. 0,01:1 til ca. 2:1, og hvori hvori epihalohydrinen er epiklorhydrin.

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